$P(-2\leq B_{t}\leq 2\,\forall t\in [0,1])=P(\inf_{t\in[0,1]}B_{t}\geq -2\, , \,\sup_{t\in[0,1]}B_{t}\leq 2)$
Now just see that $P(\inf_{t\in[0,1]}B_{t}\geq -2\, , \,\sup_{t\in[0,1]}B_{t}\leq 2)\leq P(\sup_{t\in[0,1]}B_{t}\leq 2)$ .
Now $\sup_{t\in[0,1]}B_{t}\sim |B_{1}|\sim |X|$ where $X\sim N(0,1)$ .
[$\sup_{t\in[0,1]}B_{t}$ is just the Running Maximum of the Brownian motion and it has the same distribution as $|B_{1}|$]
So what you want is $P(|X|\leq 2)= 1-P(|X|\geq 2) = (1-2\cdot P(X\geq 2))$
Now just use a tail estimate for the Gaussian, namely $\int_{y}^{\infty}\frac{1}{\sqrt{2\pi}}\exp(-\frac{x^{2}}{2})\,dx \leq \frac{1}{y\sqrt{2\pi}}\exp(-\frac{y^{2}}{2})$
So $P(X\geq 2) \leq \frac{1}{2\sqrt{2\pi}}e^{-2}\leq \frac{1}{2\sqrt{2\pi}}$
Hence $-2P(X\geq 2)\geq -\frac{1}{\sqrt{2\pi}}$
Thus $P(|X|\leq 2)\geq 1-\frac{1}{\sqrt{2\pi}}$
And hence you have the required bound.
Note that using the Gaussian Tail Estimate, we could have gotten a better bound , namely,
$P(|X|\leq 2)\geq 1-\frac{1}{e^{2}\sqrt{2\pi}}$ which is obviously better than what is being asked and hence $P(-2\leq B_{t}\leq 2\,\forall t\in[0,1])\geq 1-\frac{1}{e^{2}\sqrt{2\pi}}$