The geometric distribution tells us that when you have independent events and you want to obtain the expected value till you have a success, you know that E[x] = 1/p.
P(2 sixes in a row) = (1/6)(1/6) = 1/36
Since rolling dice is independent trials, why is the expected number of rolls till you get 2 6s not equal to 1/(1/36), or 36? The answer is actually 42.