For $\text{mod 5}$,
$[1] = \{\dotsc, -4, 1, 6, \dotsc\}$
So, we can write,
$$6\equiv1\ \text{(mod 5)}\tag{1}$$
Which means that I can substitute $1$ for $6$ (and vice versa) anywhere I see it $(\text{mod 5})$. So, consider the example below:
$$6^{719} \ \text{mod 5}$$
$$=1^{719} \ \text{mod 5}$$
$$=1\ \text{mod 5}$$
$$=1$$
And this is the correct answer.
Now, consider another example,
$$2^6\ \text{mod 5}$$
$$=2^1\ \text{mod 5}\ \ \text{[Using (1)]}$$
$$=2$$
However, this is a wrong answer. The correct answer is 4. Why is substituting 1 for 6 not working in this case? Aren't they congruent to each other?