We define $X^*$ as the union $I\cup\{z\}$ such that a neighborhood base $\mathcal B_z$ of $z$ is given by those sets containing $z$ whose intersection with $I$ is an open dense subset of $I$, and a neighborhood base $\mathcal B_x$ of $x\in I$ is the usual neighborhood filter.
To see that this defines a topological space on $X^*$ via neighborhood filters, you have to show two things:
- Each neighborhood base is indeed a filterbase, i.e. for all $A,B\in\mathcal B_x$ we have $A\cap B\supseteq C$ for some $C\in\mathcal B_x$.
- For each $A\in\mathcal B_x$ there is a $B\in\mathcal B_x$ s.t. for each $y\in B$ there is a $C\in\mathcal B_y$ with $C\subseteq A$.
Both properties are easy to verify in this situation.
Let $\tau^*$ be the topology on $X^*$ and $\tau$ the topology on $I$. Note that $\tau^*$ induces the original topology on $I$. Therefore $I$ is still compact in $X^*$, but it is not closed since $\mathrm{cl}(I)=X^*$. So $X^*$ is not a $KC$ space.
Now let $(x_n)_n$ be a sequence in $X^*$ converging to a $z$ and to a point $y\in I$. Since $I$ is open, the sequence is eventually in $I$, so we can assume that it is contained entirely in $I$. Since $I$ is $T_2$, there can be no cluster point $x\ne y$ in $I$. Then $(x_n)_n\cup\{y\}$ is closed (in $I$) and nowhere dense, hence its complement is open and dense and thus constitutes a neighborhood of $z$. But this means that $(x_n)_n$ cannot converge to $z$ and, as already mentioned, its limit in $I$ is unique. So $X^*$ is a $US$-space.
Although, this does not answer your question on why no sequence in $I$ converges to $z$, it at least shows that there are $US$-spaces that are not $KC$-spaces.