$\def\erfc{\operatorname {erfc}}$
If there were elementary functions, then the series coefficients could be expanded, but we have $\erfc(a)$. Here is another explicit solution using a Dirac $\delta(t)$ integral. We use the following result:
$$\int_0^1\delta(\sqrt\pi\erfc(t)-2t)dt=\frac12\left(1-\frac1{e^{a^2}+1}\right)=0.27614\dots$$
Now apply a $\delta(t)$ series expansion:
$$a=\sqrt{\ln\left(\frac1{1-\frac1\pi\sum\limits_{n\in\Bbb Z}\int_0^1 \cos(n(\sqrt\pi\erfc(t)-2t))dt}-1\right)}$$
which converges, but slowly. A direct approach is:
$$\int_0^1t\left(e^{-t^2}+1\right)\delta(\sqrt\pi\erfc(t)-2t)dt=a$$
Therefore we use another series expansion:
$$a=\sum_{n\in\Bbb Z}\int_0^1 t\left(e^{-t^2}+1\right) e^{i n(\sqrt\pi\erfc(t)-2t)}dt=\frac1\pi\left(1-\frac1{2e}+2\sum_{n=1}^\infty\int_0^1 t\left(e^{-t^2}+1\right)\cos(n (\sqrt\pi\erfc(t)-2t))dt\right)$$
Although slow, it works here. Now to integrate and expand the coefficients.