Assuming we take $x$ and $y$ to be non-negative integers, we can proceed quite directly.
Let $n$ represent an arbitrary natural number we'd like to represent in this fashion. The case where $n$ is even works out rather immediately, since if $n$ is even then $n = 2k$ for some positive integer $k,$ so let $x = k, y = 0$ and $2(k) + 3(0) = 2k = n.$
If $n$ is odd, then $n = 2k + 1$ for some integer $k,$ and $n \geq 3$ implies $k \geq 1.$ We know the odd $1$ left over has to come from a $3,$ so we can rearrange our form for $n$ into $n = 2k + (- 2 + 2) + 1 = (2k - 2) + 3 = 2(k-1) + 3(1),$ and because $k \geq 1$ we have $k - 1 \geq 0,$ so $x = k - 1, y = 1$ gives us nonnegative solutions for $x$ and $y.$
Now because all natural numbers are either even or odd, and the only restriction on our natural value $n$ was that it was greater than $1,$ this concludes the proof that all natural numbers greater than $1$ can be represented in this form.
However, this does not guarantee that the breakdowns given in this proof are optimal. For instance, these procedures would break $n = 6$ into three twos, when it's rather clear the optimal grouping would be two threes. In general, we should be able to see that the smallest combined value for $x$ and $y$ comes from when we maximize the number of $3$s used, instead of $2$s as we are in our procedure. We can adjust for this by simply shifting from letting the number of $3$s determine the remainder mod $2,$ we can let the $2$s determine the remainder mod $3,$ and fill the rest with as many $3$s as possible.
In case this is a homework problem I'll hold off from undergoing this process myself for now, but I would suggest carrying out the analogue of the odd-even argument with the remainders of $0, 1,$ and $2$ mod $3$ instead. This will give you representations which maximize $y,$ which I claim would minimize $x + y,$ the total number of rounds. (leaving out the proof for now for the sake of time)