If you look at the number of Sylow $2$-subgroups of a simple group $G$ of order $168$, you know that it divides $21$. The group $G$ acts transitively on the set $\mathrm{Syl}_2(G)$ of Sylow $2$-subgroups by conjugation, so you get $|\mathrm{Syl}_2(G)|$ equals either $7$ or $21$, as $G$ simple cannot act transitively on a set of order $3$.
Now restrict this action to a Sylow $2$-subgroup $S$ of $G$. Its fixed points are the Sylow $2$-subgroups normalized by $S$. If $S$ normalizes $T$ then $S\cdot T$ is a $2$-subgroup containing $S$, implying $S=T$ as $S$ is a maximal $2$-subgroup of $G$. The other orbits of $S$ have order $2$, $4$ or $8$, but as neither $7$ nor $21$ equals $1\bmod 8$, there is an orbit of length $2$ or $4$. So there is an element $s\in S\setminus\{1\}$ and a Sylow $2$ subgroup $T\ne S$ such that $s$ normalizes $T$. As $\langle s, T\rangle$ is a $2$-subgroup and $T$ a maximal $2$-subgroup, we get $s\in S\cap T$.
We may assume that $s$ has order $2$ (otherwise take $s^2$), which implies that $s$ is central in both $S$ and $T$, UNLESS the Sylow $2$-subgroups are dihedral (which we now assume not to be). The centralizer $C:=C_G(s)$ of $s$ in $G$ contains both $S$ and $T$, so it has at least two Sylow $2$-subgroups. As $G$ is simple, the order of $C$ is $24$, and $C$ has three Sylow $2$-subgroups. The kernel $K$ of the transitive action of $C$ on the sets of its Sylow $2$-subgroups has order $4$, contains $s$, and $C/K = S_3$ the symmetric groups on $3$ elements. A Sylow $3$-subgroup $D$ of $C$ lies in the preimage of $A_3$ in $C$, centralizes $s$, and hence is normal in $C$.
$C$ is self-normalizing of index $7$, so look at the intersection of $C$ with one of its conjugates $C'\ne C$. If $C\cap C'$ contains an element of order $3$, hence $D$, then both $C$ and $C'$ normalize $D$ contradicting $G$ simple. If $C\cap C'$ contains an element of order $2$, than its centralizer contains all Sylow $2$-subgroups of $C$ and $C'$ (as they are assumed not to be dihedral), contradicting $G$ simple.
Hence $C$ intersects all its conjugates trivially, and the order of the union of all conjugates of $C\setminus\{1\}$ is $7\cdot 23 = 161$, showing that $G$ has a normal Sylow $7$-subgroup, contradicting the simplicity of $G$.