No, and we can say more.
A smooth manifold $M$ admits a Lorenztian metric iff (a) it is noncompact and/or (b) its Euler characteristic, $\chi(M)$ vanishes (see O'Neill, $\S$5, Proposition 37). On the other hand, the Euler characteristic of every odd-dimensional manifold is zero. So, a smooth manifold $M$ admits no Lorenztian metric iff
- $M$ is compact,
- $\dim M$ is even, and
- $\chi(M) \neq 0$.
In particular, compact surfaces of nonzero Euler characteristic, e.g., the $2$-sphere, admit no semi-Riemannian metric of indefinite signature.
I don't know in general which smooth manifolds satisfying (1)-(3) of dimension $\geq 4$ admit a semi-Riemannian metric of indefinite (and hence necessarily non-Lorentzian) signature, but even-dimensional spheres, for example, admit no indefinite metric.
O'Neill, Semi-Riemannian Geometry, with Applications to General Relativity (1983).
See also: Manifolds that admit Lorentzian metrics?