Your approach is valid, however arguing that the "total number of outcomes" is large is not a good justification for using the central limit theorem - by that logic you should be able to approximate any continuous distribution, which has (uncountably) infinite possible outcomes by a normal distribution, which is not true.
The random variable whose distribution you want to find is $S_n = X_{1} + \dots + X_{n}$, where the $X_{i}$ are iid and uniformly distributed on $\{1,\dots,6\}$. Using the normal distribution as an approximation via the central limit theorem is justified when $n$ is large, but here $n=10$, so it's at least debatable whether that counts as large.
Also, in this case one can give the exact solution. We can enumerate all the possibilites for the sum being $35$ with integers $k_{1},\dots,k_{10}$ in $\{1,\dots,6\}$ such that
$k_{1} + \dots + k_{10} = 35$. Call this number $K$. Then $K$ is equal to the
coefficient of $X^{35}$ in the polynomial $(X + X^2 + \dots + X^{6})^{10}$,
which can be rewritten as $X^{10} (1 + X + \dots + X^{5})^{10}$. We are
therefore looking for the coefficient of $X^{25}$ in the polynomial $(1+X+\dots+X^{5})^{10}$, which is a stars and bars problem with upper bound and can be solved e.g. as in this answer. Applying the formula from this answer, we obtain
$$K = \sum_{q=0}^{4} (-1)^{q}\binom{10}{q}\binom{25 - 6q + 9}{9} = 4395456$$
The probability then comes out as $K\cdot 6^{-10} \approx 0.0727$.
The normal approximation you gave, centered around 35 (as @drhab suggests) gives $\mathbb{P}(34.5 < X < 35.5) \approx \mathbb{P}(-\frac{1}{10.8} < Z < \frac{1}{10.8}) \approx 0.0737$, so it's actually fairly good.