If $\mu$ is a measure on a ring $R$, $A\subset E$ where $E\in \sigma(R)$ and $\mu^*(E)<\infty$, then $A$ is $\mu^*$ measurable if and only if $\mu^*(E) = \mu^*(A) + \mu^*(E-A)$ (1).
I would like to prove the $\Leftarrow$ implication, but I'm lost on what I have to consider. Specifically, if (1) holds I have to prove
$$ \mu^*(B) = \mu^*(B\cap A) + \mu^*(B\cap A^c) $$
for all $B\in\mathcal{H}(R)$ ($\supset \sigma(R)$). My problem is that I don't know how to relate $B$ with equation (1). For sure $B = (B\cap A)\cup (B\cap A^c)$, but more than that I wouldn't know how to continue.
EDIT:
So this is how far I am right now. I don't know if it's ok the reasoning though.
Let $\mathcal{H}$ be the hereditary class of sets that can be countably covered by elements of a ring $\mathcal{R}$. Let $\mathcal{M}$ be the class of $\mu^*$-measurable sets, i.e. $H\in \mathcal{H}$ is $\mu^*$-measurable in case
$$ \mu^*(B) = \mu^*(B\cap H) + \mu^*(B\cap H^c) $$
for all $B\in \mathcal{H}$. The following chain is known $\sigma(R)\subset \mathcal{M} \subset \mathcal{H}$. Thus, $E$ is $\mu^*$-measurable, i.e.
$$ \mu^*(B) = \mu^*(B\cap E) + \mu^*(B\cap E^c). $$
If we can prove $\mu^*(B) \geq \mu^*(B\cap A) + \mu^*(B\cap A^c)$ then we are done. Since $E = (E-A) \cup A$ we have
\begin{equation} \begin{split} \mu^*(B) &= \mu^*[B\cap((E-A) \cup A)] + \mu^*(B\cap E^c)\\ &\geq \mu^*(B\cap A) + \mu^*(B\cap E^c).\\ \end{split} \end{equation}
Up to here, I haven't used condition (1), so I guess one needs to use it in writting $E^c$ as a "function" of $A^c$ but I'm lost on how to write this relationship.