The connection is the following one. A linear function from $\mathbb{R}$ to $\mathbb{R}$, where $\mathbb{R}$ is considered as a vector space over itself, is a function $f$ that satisfies the following two equations:
\begin{equation}
\forall x,y \in \mathbb{R},\qquad f(x+y) = f(x) + f(y)\;,\qquad (1)
\end{equation}
\begin{equation}
\forall x,\lambda \in \mathbb{R},\qquad f(\lambda \cdot x) = \lambda \cdot f(x)\;. \qquad (2)
\end{equation}
Notice that $(2)$ is equivalent to
\begin{equation}
\forall x \in \mathbb{R}, \qquad f(x) = x \cdot f(1)\;. \qquad (3)
\end{equation}
We may wonder if $(1)$ implies $(3)$. After all, if we only assume that $(1)$ holds, we have
- Using induction, $ \forall n \in \mathbb{N}, \forall x \in \mathbb{R}, f(n \cdot x) = f(\sum_{k=1}^n x) = \sum_{k=1}^n f(x) = n \cdot f(x)$.
- $\forall n \in \mathbb{N}, f(1) = f(n \cdot \frac{1}{n}) = n \cdot f(\frac{1}{n})$, which implies $\forall n \in \mathbb{N}, f(\frac{1}{n}) = \frac{f(1)}{n}$.
- $\forall m,n \in \mathbb{N}, f(\frac{m}{n}) = f(m\cdot\frac{1}{n}) = m\cdot f(\frac{1}{n}) = \frac{m}{n}\cdot f(1)$.
- $f(0) = f(0+0) = f(0)+f(0)$, which implies $f(0) = 0$.
- $\forall m,n \in \mathbb{N}, f(-\frac{m}{n}) = f(-\frac{m}{n})+f(\frac{m}{n})-f(\frac{m}{n}) \\= f(-\frac{m}{n}+\frac{m}{n}) -f(\frac{m}{n}) = f(0) -f(\frac{m}{n}) = 0 - f(\frac{m}{n}) = -f(\frac{m}{n}) = -\frac{m}{n}\cdot f(1)\;.$
It follows that $\forall q \in \mathbb{Q}, f(q) = q \cdot f(1)$, so $(3)$ is "almost" implied by $(1)$.
But there's a catch. Pick $\sqrt{2}$. Then for each $q \in \mathbb{Q}$ we have that $q \neq -\sqrt{2}$. This implies that $1$ and $\sqrt{2}$ are linearly independent over $\mathbb{Q}$. Then, we can build $\tilde{f} \colon \mathbb{Q}[\sqrt{2}] \to \mathbb{R}$ as the unique linear function on $\mathbb{Q}[\sqrt{2}]$ (as a vector space over $\mathbb{Q}$) such that $\tilde{f}(1) = 1 = \tilde{f}(\sqrt{2})$. This function satisfies $\forall x,y \in \mathbb{Q}[\sqrt{2}], \tilde{f}(x+y) = \tilde{f}(x)+\tilde{f}(y)$ but fails to satisfy $\forall x \in \mathbb{Q}[\sqrt{2}], \tilde{f}(x) = x\cdot \tilde{f}(1)$, since $\tilde{f}(\sqrt{2}) = 1 \neq \sqrt{2} = \sqrt{2} \cdot 1 = \sqrt{2} \cdot \tilde{f}(1)$.
Now, we may repeat the process adding another number $\alpha \in \mathbb{R}$ such that $\alpha \notin \mathbb{Q}[\sqrt{2}]$ and extending the previous function so to preserve the property $$\forall x,y \in \mathbb{Q}[\sqrt{2}, \alpha], f(x+y) = f(x)+f(y).$$
Ideally, we want to continue this process of extension adding numbers until we "fill" the whole $\mathbb{R}$, so as to obtain in the end a function that satisfies $(1)$ but not $(3)$.
However, it is not clear how this can be formally done.
It's here that Hamel bases come to our aid: they provide a formal way to do that.
Consider $\mathbb{R}$ as a vector space over the field $\mathbb{Q}$. Since $1$ and $\sqrt{2}$ are linearly independent over $\mathbb{Q}$, we can build a Hamel basis for $\mathbb{R}$ over $\mathbb{Q}$ containing them, say $(e_i)_{i \in I}$, where $I$ is some set. Then, we can define a linear function (thinking $\mathbb{R}$ as a vector space over $\mathbb{Q}$), say $\bar{f} \colon \mathbb{R} \to \mathbb{R}$, that extends our previously defined linear function $\tilde{f} : \mathbb{Q}[\sqrt{2}] \to \mathbb{R}$. We can do this specifying its values over the base $(e_i)_{i \in I}$. For example, $\bar{f}(1) = 1 = \bar{f}(\sqrt{2})$, and $\forall i \in I \backslash \{1,\sqrt{2}\}, \bar{f}(e_i) = e_i$.
This way, by construction $\bar{f}$ satisfies $(1)$, but we already know that $(3)$ is violated since $\bar{f}$ is an extension of $\tilde{f}$, so that $\bar{f}(\sqrt{2}) = \tilde{f}(\sqrt{2}) \neq \sqrt{2} \cdot \tilde{f}(1) = \sqrt{2} \cdot \bar{f}(1)$.
Some final (exotic) remarks:
- $\bar{f}$ is discontinuous everywhere.
- If we impose that $(1)$ holds and that $f$ has to be continuous at some point $x\in\mathbb{R}$, then we can prove that $(3)$ (or, equivalently, $(2)$) holds.
- The continuous linear functions from $\mathbb{R}$ to $\mathbb{R}$ where $\mathbb{R}$ is considered as a vector space over $\mathbb{Q}$ coincide with the linear functions from $\mathbb{R}$ to $\mathbb{R}$ where $\mathbb{R}$ is considered as a vector space over $\mathbb{R}$.