The answer is easy to calculate.
638/1024, roughly 62.3% probability.
Say your outcomes are A, your friend's are B. There are 5 cases for B that you must beat. For each of B's outcomes, find the probability that you succeed. These are all specific cases, so they will have low-ish probabilities. Then add those together for the total probability of winning.
B = 0 Heads, A = 1+ (one or more) Heads:
P(B zero) = (1/2)^4 (4C0) = 1/16
P(A not zero) = 1 - [(1/2)^6 (6C0)] = 1 - 1/64 = 63/64
Multiply, to get P(you win) for this case.
(1/16)(63/64) = 63/1024
B = 1, A = 2+ :
P(B=1) = (1/2)^4 (4C1) = 4/16
Four ways to get one Heads.
P(A not 0 or 1)= 1 - [(1/2)^6 (6C1)] - 1/64 = 1 - 6/64 - 1/64 = 57/64
Six ways to get one Heads, still only one way to get zero Heads. Keep subtracting more and more from one, for each new case.
Multiply again.
(4/16)(57/64) = 228/1024
B = 2, A = 3+ :
P(B=2) = 6/16
P(A not 0,1,2) = 1 - 15/64 - 6/64 - 1/64 = 42/64
Therefore, (6/16)(42/64) = 252/1024
B = 3, A = 4+ :
P(B=3) = 4/16
P(A not 0,1,2,3) = 1 - 20/64 - 15/64 - 6/64 - 1/64 = 22/64
So, (4/16)(22/64) = 88/1024
B = 4, A = 5+ :
P(B=4) = 1/16
P(A not 0,1,2,3,4) = 1 - 15/64 - 20/64 - 15/64 - 6/64 - 1/64 = 7/64
And, (1/16)(7/64) = 7/1024
Finally, the sum is 638/1024
≈ .623