It is not clear how to adapt the usual Sylverster's criterion to non-symmetric matrices. For instance, consider the matrix
$$ M= \begin{pmatrix} 1 & a \\ b & 1 \end{pmatrix}, $$
where $a$ and $b$ will be fixed later. The principal minors are $1$ and $1-ab$. But for the symmetric matrix
$$ \frac{M+M^T}{2} = \begin{pmatrix} 1 & (a+b)/2 \\ (a+b)/2 & 1 \end{pmatrix}, $$
the principal minors are $1$ and $1-((a+b)/2)^2$.
This way, the map $x \mapsto x^t M x$ is positive definite if and only if $1-((a+b)/2)^2>0$. This is not something you can check only looking at $1-ab$. For instance, if $a=0, b=10$, then both $1$ and $1-ab$ are positive, but $x \mapsto x^T M x$ is not positive definite.