When $A$ is skew-symmetric, then $Q = e^{A t}$ is orthogonal or $Q^T Q = I$.
(For a linear autonomous system $\dot{x} = A x$, the fundamental matrix of the system is $\Phi(t) = e^{A t}$.)
To prove this identity, I make use of the result $$ \left( e^{P} \right)^T = e^{P^T} \tag{1} $$ for any matrix $P$.
Since $e^P$ can be expressed as the uniformly convergent series, $$ e^P = \sum\limits_{k = 0}^\infty \ {P^k \over k!}, $$ it follows that $$ \left( e^P \right)^T = \left( \sum\limits_{k = 0}^\infty \ {P^k \over k!} \right)^T = \sum\limits_{k = 0}^\infty \ {(P^k)^T \over k!} = \sum\limits_{k = 0}^\infty \ {(P^T)^k \over k!} = e^{P^T} $$
Assume that $A$ is skew-symmetric. Then $$ A^T = -A $$
Define $$ Q = e^{A t} $$
Then we have $$ Q^T = e^{( A t)^T} = e^{A^T t} = e^{- A t} = \left( e^{A t} \right)^{-1} = Q^{-1} $$
Thus, it follows that $$ Q^T Q = Q^{-1} Q = I $$ showing that $Q$ is orthogonal.
I hope that this proof is OK!