Given the subject of Analytic Geometry and the discussion of vectors as geometric objects, I doubt the books starts off with introducing the concept of vector spaces in abstract. It most likely is concerned only with a very specific $3$-dimensional vector space over the real numbers.
Unfortunately, those who have lived for years in the canopy of the tree of mathematics exploring its myriad twisted pathways and the bright green foliage all around tend to forget that from the bottom, its a big brown trunk with a few large branches barely within reach.
The result can be shown in two ways at this level.
Algebraically, $-\vec 0 = \vec 0$ by definition, and adding $\vec u$ to both sides of $\vec u = -\vec u$ gives
$$\begin{align}\vec u + \vec u&= -\vec u + \vec u\\2\vec u &= \vec 0\\\vec u &= \frac 12 \vec 0\\\vec u &= \vec 0\end{align}$$
Geometrically, if $\vec u \ne \vec 0$, then $\vec u$ is a line segment with $\vec 0$ as one endpoint, and by definition $-\vec u$ is the line segment extending from $\vec 0$ in the other direction on the same line and having the same length. Because these two line segments extend in opposite directions, they are not the same. So if $\vec u \ne 0$, then $\vec u \ne -\vec u$. But also by definition $-\vec 0 = \vec 0$.
At least that is one way of seeing it geometrically. Not everybody defines the geometric vector space in exactly the same way, so your definitions may be a bit different, in which case, my description is not strictly by your definition, but instead is a fairly easy conclusion from your definition. But without knowing your definition, I cannot say more.