Although @MishaLavrov has already provided a solution, I'll show here a pretty mechanical (and general!) method how to detect, that a second solution for
$$ 12^x - 5^y = 19 \tag 1$$
beyond $(x,y)=(2,3)$ cannot exist. 1)
We find easily that $19 = 144 - 125 = 12^2-5^3$. Thus we have indeed
$$ 12^x - 5^y = 12^2-5^3 \tag 2 $$
This can be reformulated into
$$ 12^x-12^2 = 5^y-5^3 $$
$\qquad$ and then $${12^u-1 \over 5^3 } = {5^v-1 \over 12^2} \tag 3 $$
$\qquad \qquad $ Here we want, that $(u=x-2,v=y-3) \gt (0,0)$.
In the lhs, the numerator to have the primefactor $5$ to the power of $3$ we must have $u = 4 \cdot 5^2$ or a multiple of this, so we could introduce this restriction on $u$
$$
{12^{4 \cdot 5^2 \cdot u_1}-1 \over 5^3 } = {5^v-1 \over 12^2} \tag {4a}
$$
In the rhs we can determine a restriction for $v$ analoguously: to have the primefactors $12^2=2^4 \cdot 3^2$ in the numerator, we must have that $v=2^2 \cdot 3$ or a multiple of this, so we introduce this restriction as well:
$$\underset{\text{lhs}}{\underbrace{ {12^{4 \cdot 5^2 \cdot u_1}-1 \over 5^3 } }} =\underset{\text{rhs}}{\underbrace{ {5^{2^2 \cdot 3 \cdot v_1}-1 \over 12^2} }} \tag {4b}
$$
Now, if $u_1=1$ and $v_1=1$ have their minimal values, we have in the lhs and the rhs the following primefactor-decompositions:
$$ \begin{array} {ll}
\text{lhs}:& & 13\;\; .11.29.101.1201.1951.19141.22621.60601.73951.\text{<big>} \\
\text{rhs}:& & 13\;\; .7.31.601
\end{array} \tag 5$$
The difference between the primefactorization of the lhs and of the rhs must now be compensated by expanding the exponents $u_1$ and $v_1$ appropriately to get equality.
But before we start to do this (possibly iteratively) we would look, how an unsolvable contradiction for the equation between lhs and rhs could possibly occur: if the involved adaption of exponents/primefactors includes either, that the lhs get one more primefactor of $5$ such that it becomes to be divisible by $5^4$ instead of $5^3$ - or that the rhs is forced to include exponents in $v_1$ such that the (composite) factor $12$ occurs to the third power instead of second power (or simply the primefactor $2$ to the $5$'th power or the primefactor $3$ to the third power which would already suffice for an "unsolvability contradiction").
To make it short, we find in the lhs in (4b) (resp. (5)) the primefactor $p=1201$. Thus we must expand the exponent in the rhs such that it shall occur as well there. For this, we must expand the exponent to include the "multiplicative order" $\pmod 5$ of $p=1201$ which is $o_5=600$. If we include this value $o_5$ into the exponent in the rhs we get the primefactorization
$$\begin{array} {} \Large \text{rhs}&=& \Large {5^{\text{lcm} (2^2 \cdot 3, 600)}-1 \over 12^2}
\\ &=& \quad 2 \quad .7.11.13.31.41.61.71.101.151.181.241... \\
&&.251.313.401.521.601.\quad 1201 \quad.1741.1901.\text{<big>}
\end{array} \tag 6$$
We have thus indeed adapted the rhs to contain the primefactor $1201$.
But, as a sideeffect, we have also one more primefactor $2$, and this makes the whole rhs being even.
This expresses contradiction, or condition of impossibility: the lhs can never be even (except both lhs & rhs are zero), so because the primefactor $p=1201$ is unavoidedly in the lhs, it must as well be in the rhs, and if it is in the rhs, then as a "collateral effect" the rhs moreover becomes even, which the lhs cannot be.
So this is enough to prove there is no additional solution beyond $(x,y)=(2,3)$.
1)The principle of this method has been applied several times already here in MSE at least by Will Jagy and by myself, perhaps later I can add some links.