The idea of Riemannian Geometry is motivated by the 'normal' differential geometry sitting in $\mathbb{R}^n$. You probably learned something like the first fundamental form and the second fundamental in studying the hypersurface. The first fundamental form $g$ in the Euclidean space is a positive definite 2-tensor in term of local coordinate. $$g=g_{ij}\, du^i\otimes du^j$$ where the $g_{ij}=\langle \frac{\partial F}{\partial u_i},\frac{\partial F}{\partial u_j}\rangle$ where $\langle \cdot,\cdot\rangle$ is the standard dot product.
Then , we can use the first fundamental form to define angle and length s.t it encodes the geometric property of the hypersurface for example Volume, length of the curve, etc. After that, by Theorema Egregium, the Gaussian curvature depends on the first fundamental form only. It means that the curvature of the hypersurface can be measured intrinsically.
Under this consequence, we assume the manifold does not sit inside a Euclidean Space. But now we can measure the curvature of the manifold intrinsically, if we can define a positive definite 2 tensor on the manifold which is called Riemannian metric (The first fundamental form manifold version)
For example, we can parameterize a round sphere $\mathbb{S}^2$ by spherical coordinate with radius $R$ its $F(\theta,\varphi)=(R\cos\theta\sin\varphi,R\sin\theta\sin\varphi,R\sin\varphi)$ Then consider their partial derivative and dot it together we will get the first fundamental form explicitly $$g=g_{\theta\theta}d\theta\otimes d\theta+g_{\theta\varphi}d\theta\otimes d\varphi+g_{\varphi\theta}d\varphi\otimes d\theta+g_{\varphi\varphi}d\varphi\otimes d\varphi=R^2d\varphi\otimes d\varphi+R^2\sin^2\varphi d\theta\otimes d\theta$$
Under the Riemannian metric, we can define length, volume, curvature intrinsically.
Therefore, if a smooth manifold $M$ endow a positive definite inner product (Riemannian metric) on the manifold $g$. We name this pair $(M,g)$ is a Riemannian Manifold.