I suppose this is not an easy question unless we formally define what counts as a theorem. For the purpose of this question, let us conservatively suppose that we are taking ZFC as our foundation, and assume that every theorem is some implication of the axioms.
With that in mind, my immediate thought is that indeed the set of provable theorems must be countable, as the set of (finite) first order logic statements are countable.
However, such argument seems valid on the prior assumption that every theorem can be expressed with a finite amount of first order logic symbols, and I am not convinced that this is true.
Thus, are there provable theorems which cannot be expressed by a finite amount of symbols? In other words, do the axioms of ZFC imply the existence of some knowable tautology that is beyond that which first order logic could express with a finite amount of symbols?