Please see diagram below.
I am trying to find an expression for $θ$ that makes the area of the bottom region $(2a)$ equal to the sum of the other two areas $(a)$. Assume this is a unit circle, so $r=1$.
Diagram not drawn to scale
The area of circular segment $a$ of a unit circle is: $A_a = \frac{θ_1 - sin(θ_1)}{2}$
Note that this $θ_1$ is not the $θ$ shown in the first diagram, but that: $θ_1 = π - θ$
The area of circular segment $2a$ of a unit circle is $A_{2a} = \frac{θ_2 - sin(θ_2)}{2}$
Let: $A_a = \frac{A_{2a}}{2}$
Then we have: $\frac{θ_1 - sin(θ_1)}{2} = \frac{θ_2 - sin(θ_2)}{4}$
We know that: $θ_1 + \frac{θ_2}{2} = π$
Solving for $θ_1$ we get: $θ_1 = π - \frac{θ_2}{2}$
After substituting we get:
$\frac{(π - \frac{θ_2}{2}) - sin(π - \frac{θ_2}{2})}{2} = \frac{θ_2 - sin(θ_2)}{4}$
If I could solve this for $θ_2$, finding $θ$ would be trivial.
The Inscribed Angle Theorem says that: $θ = \frac{θ_2}{2}$
I was able to get what looks like a numerical approximation using wolframalpha, but I can't find a closed form solution. I think $θ$ works out to be: $1.2473826912977909520$ radians or $71.46976364903345985$ degrees