Update
What I was trying to do here was to come up with an axiom that could replace the axiom of countable choice. Although the effort went down in flames, I now more strongly appreciate and respect the set theoretic axiomatic fortress that has been erected over the past century or so.
I tried again (being more careful this time), defining $\text{sub-}\omega$ injections into $\Bbb N$ (as Asaf remarked, bijections can't work) and attempting to write up a new axiom. But all I wound up with is just another way of saying that the union of countable set is countable is because because.
Axiom
Let $(A_k)_{k\in \Bbb N}$ be a family of disjoint sets $A_k$ and $B$ a set such that
$\tag 1 \text{There exists an injective mapping from } A_0 \text{ into } B$ $\tag 2 \text{Every injective map on } \bigcup_{k \lt n} A_k \text{ to } B \text{ can be extended to an injection on } \bigcup_{k \le n} A_k $
Then there exist and injection of $\bigcup_{k = 0}^{\infty} A_k$ into $B$.
Question: Can we use this axiom to prove that the union of countably many countable sets is countable?
My work
I've already sketched out such a proof and will provide my answer here if this question can be answered in the affirmative.
If someone's answer would make my argument redundant, I will accept their answer (besides giving it an upvote).