Item 1: The Theorem 13.18 is about $\sigma$-finite measure spaces and $L^p$, where $1\leq p < \infty$. The proof begins by considering the case of finite measure spaces.
So, let $(X, \mathcal{M}, \mu)$ be a measure space and $\mu(X) <\infty$.
Given any $g \in L^\infty$, we have that there is $M>0$ such that $|g| \leq M$ almost everywhere. So, given any $p$, $1\leq p < \infty$, we have:
$$\int_X |g|^p d\mu \leq \int_X M^p d\mu = M^p \mu(X) < \infty$$
So, we have that $L^\infty \subseteq L^p$.
Now, given any $f \in L^p$, then, for all $n \in \Bbb N$, let $f_n= f \cdot \chi_{\{x \in X : |f(x)| \leq n\}}$. It is easy to see that $f_n \in L^\infty$.
Note that
$| f - f_n|^p = |f|^p \cdot \chi_{\{x \in X : |f(x)| > n\}}$. Since $f \in L^p$, $f$ is finite almost everywhere, so, as $n \to \infty$, we have $|f|^p \cdot \chi_{\{x \in X : |f(x)| > n\}} \to 0$ almost everywhere. Note also that $|f|^p \cdot \chi_{\{x \in X : |f(x)| > n\}} \leq |f|^p$ and, since $f$ is in $L^p$,we have that $|f|^p \in L^1$. Then, applying the Dominated Convergence Theorem, we have
$$ \lim_n \int_X | f - f_n|^p d\mu = \lim_n \int_X |f|^p \cdot \chi_{\{x \in X : |f(x)| > n\}} d\mu = \int_X 0 \ d\mu =0$$
Remark: After proving $L^\infty \subseteq L^p$, if you know that the simple functions (which are functions in $L^\infty$) are dense in $L^p$, you can use this fact to deduce that $L^\infty$ is dense in $L^p$.
Item 2: You ask:
"because two functionals $\Gamma_1, \Gamma : L^{p} \to \mathbb{F}$ agree on a dense subspace of $L^{p}$ how that implies they agree on whole domain $L^{p}$?"
The answer is yes, because the functionals $\Gamma_1, \Gamma : L^{p} \to \mathbb{F}$ in Theorem 13.18 are continuous linear functionals.
In fact, as QuantumSpace noted, this is a general property:
Let $X$ and $Y$ be metric spaces and let $D$ be a dense subset of $X$. Then, for any two continuous functions $f: X \rightarrow Y$ and $g:X \rightarrow Y$, if $f$ and $g$ agrees on $D$ then $f=g$
Proof: Given any $x \in X$, let $\{x_n\}_n$ be a sequence of points in $D$ such that $x_n \to x$. Then
$$ f(x) = \lim_n f(x_n) = \lim_n g(x_n) =g(x) $$