Addition modulo $n$ is basically an equivalence relation on $\mathbb Z$ (the set of integers). Let me define the equivalence relation here:
Let $n\in \mathbb Z^+$. On $\mathbb Z$, define a relation $\sim$ such that for all $a$ and $b$ in $\mathbb Z, a\sim b$ if and only if $n$ divides $(a-b)$.
Verify that this this relation $\sim$ is reflexive, transitive and symmetric. In more words, $\sim$ is equivalence relation on $\mathbb Z$.
What is the equivalence class of $a\in \mathbb Z$? It's precisely the set $\{a+kn:k\in \mathbb Z\}$, which is denoted by $[a]$ so called equivalence class of $a$ under addition modulo $n$.
So if $[a]=[b]$, then we mean that equivalence class of $a$ and $b$ are the same and it is possible if and only if $a\sim b$ that is when $n$ divides $(a-b)$. It is this fact that is usually denoted by: $a\equiv b \bmod n$.