By continuity of sine, it suffices to show that for any $\epsilon > 0,$ there's some integer $n$ so that $|n - (2k + 0.5)\pi| < \epsilon$ for some integer $k,$ since then $\sin n$ can be made arbitrarily close to $\sin (2k+0.5)\pi = \sin 0.5\pi = 1.$ A similar trick works for $-1.$
By dividing by $2\pi,$ it suffices to find some $n$ such that there exists a $k$ for which
$$\left| \frac{n}{2\pi} - k -\frac{1}{4}\right| < \frac{\epsilon}{2\pi}.$$
Fortunately, $1/2\pi$ is irrational, and the fractional parts of integer multiples of an irrational number are dense mod $1$ (this is Dirichlet's theorem), so it is possible to find some $n$ and $k$ positive integers making this inequality hold.