It is not correct to say that whether you are told that an ace is in the hand or whether you are told that the ace of spade is in the hand, the probability of having at least two aces is the same
Case 1: You are told that you have at least one ace
Note that in the following formula, the sample space shrinks to $\binom{52}5 - \binom{48}5$ to take into account that at least one ace must be present, and that in the numerator we need to ensure that one ace is there
$Pr = 1 - \dfrac{\binom41\binom{48}4}{\binom{52}5 - \binom{48}5},\;\approx 0.1222$
Case 2: You are told that you have the ace of spades
Sinca ace of spades is assured, the sample space is now simply $\binom{51}{4}$, and from the numerator, we just subtract $\binom{48}4$ to indicate that more aces must be present.
Thus $Pr = 1 - \dfrac{\binom{48}4}{\binom{51}4}\; \approx 0.2214$
Added approach
Since probability problems are often "tricky", here is an approach simpler to understand, though longer computationally.
Basically, the numerator will count hands with $2$ or more aces, and the denominator, hands with $1$ or more aces
Case 1: You are told that you have at least one ace
$Pr = \dfrac{\binom42\binom{48}3 + \binom43\binom{48}2 +\binom44\binom{48}1}{\binom41\binom{48}4+\binom42\binom{48}3 + \binom43\binom{48}2 +\binom44\binom{48}1}\approx 0.1222$
Case 2: You are told that you have the ace of spades
Bear in mind that you have the ace of spades and are left to pick from $51$ cards including $3$ aces
$Pr = \dfrac{\binom31\binom{48}3 + \binom32\binom{48}2 +\binom33\binom{48}1}{\binom30\binom{48}4+\binom31\binom{48}3 + \binom32\binom{48}2 +\binom33\binom{48}1} \approx 0.2214$