$\mathbb RP^k$ can be represented as the quotient space $S^k/\sim \phantom{.}$ where $\sim$ identifies antipodal points. Let $p : S^k \to \mathbb RP^k$ denote the quotient map. Let $S^k_+$ denote the closed upper hemisphere of $S^k$ which is canonicallly homeomorphic to $D^k$ via $h : S^k_+ \to D^k, h(x_1,\dots,x_{k+1}) = (x_1,\dots,x_k)$. The map
$p' : D^k \to \mathbb RP^k, p'(\xi) = p(h^{-1}(\xi))$, is a continuous surjection (note that each equivalence class with respect to $\sim$ has a representative in $S^k_+$). Since $D^k$ is compact and $\mathbb RP^k$ is Hausdorff, $p'$ is closed map and hence a quotient map. It identifies antipodal points in the boundary $S^{k-1}$ of $D^k$ and embeds the open ball $\mathring D^k$ as an open subset into $\mathbb RP^k$.
So what is the pushout of your diagram? It is the adjunction space $\mathbb RP^n \cup_p D^{n+1}$ which is obtained from the disjoint union $\mathbb RP^n \sqcup D^{n+1}$ by identifying $\xi \in S^n \subset D^{n+1}$ with $p(\xi) \in \mathbb RP^n$. Let $q : \mathbb RP^n \sqcup D^{n+1} \to \mathbb RP^n \cup_p D^{n+1}$ denote the quotient map and $q' : D^{n+1} \to \mathbb RP^n \cup_p D^{n+1}$ its restriction. It is a continuous surjection (note that each $\eta \in \mathbb RP^n$ has the form $p(\xi)$ with $\xi \in S^n$, thus $q(\eta) = q(\xi)$). Hence $q'$ is a quotient map. Clearly $q'$ is injective on $\mathring D^{n+1}$ (no identifications are made here) and $q'(\mathring D^{n+1}) \cap q'(S^n) = \emptyset$. On $S^n$ the map $q'$ identifies antipodal points and therefore $\mathbb RP^n \cup_p D^{n+1} \approx \mathbb RP^{n+1}$ by our above considerations.