I proved that the mapping $\phi: G \to \operatorname{Aut}(G)$ that sends $g \longmapsto c_g (x) = gxg^{-1}$ is a homomorphism, but I need to find a group $G$ for which this map establishes an isomorphism. I know that $S_3$ is isomorphic to $\operatorname{Aut}(G)$, but I don't know off-hand whether this bijection is the correct one. I referenced a similar answer here Proving that ${\rm Aut}(S_3)$ is isomorphic to $S_3$, but it doesn't give an explicit formula for the bijection, and though I understand that $S_3$ is generated by its transpositions and so any automorphism is determined completely by how it acts on $(12)$, $(13)$, and $(23)$, I don't understand how a bijection follows.
Updated Attempt:
I claim that $\phi: S_3 \to \mathrm{Aut}(S_3)$ sending $g \longmapsto c_g (x) = gxg^{-1}$ is an isomorphism. In general, $\phi: G \to \mathrm{Aut}(G)$ sending $g \longmapsto c_g$ is a homomorphism, so it suffices to show that $\phi$ is a bijection. We have: \begin{align*} g \in \mathrm{ker}(\phi) & \iff \phi(g) = c_g (x) = x, \; \forall x \in G \\ & \iff gxg^{-1} = x, \; \forall x \in G \\ & \iff gx = xg, \; \forall x \in G \\ & \iff g \in Z(G) = \{e\}, \end{align*} so the kernel of $\phi$ is trivial, so $\phi$ is injective. I claim that $\phi$ is also surjective. We have $S_3 = \langle a = (12), b = (13), c = (23) \rangle$, each of which has order $2$, so given $g \in S_3$, we have $g = a^i b^j c^k$ for $i,j,k \in \{0,1,2\}$. Since an automorphism $f \in Aut(S_3)$ must preserve the order of elements, $f$ must send transpositions to transpositions. Furthermore, upon fixing where $f$ send these transpositions, the rest of the map is determined. Since there are $3!$ possibilities for where to send the permutations, there are exactly $6$ automorphisms, so $|S_3| = |\mathrm{Aut}(S_3)|$. But $\phi(S_3) \leq \text{Aut}(S_3)$, so that they have the same order immediately implies that $\phi(S_3) = \text{Aut}(S_3)$, so $\phi$ is surjective, hence bijective.