Warning: DISGUSTING CASEWORK AHEAD
Rewrite the equation as $3(x_1+x_2)+x_3+x_4=30$. Now, let $a=x_1+x_2$ and $b= x_3+x_4$. Thus, we have $3a+b = 30$. So, we can easily figure that each solution pair $(a,b)$ are $(2,24),(3,21),(4,18),(5,15),(6,12),(7,9),(8,6),(9,3)$. Note that $a,b \ge 2$ because each one is the sum of $2$ naturals, which are both $1$ or greater. Now, we examine each case.
For $(2,24)$, we can make $a=2$ with the pair $(1,1)$ and make $b=24$ with pairs $(1,23)$ through $(23,1)$, which is $23$ pairs. Thus for this case we get $23$ solutions by multiplying $1$ way to make $a=2$ with $23$ ways to make $a=24$.
For $(3,21)$, we can make $a=3$ with the pairs $(1,2),(2,1)$ and make $b=21$ with pairs $(1,20)$ through $(20,1)$, which is $20$ pairs. Thus for this case we get $40$ solutions by multiplying $2$ way to make $a=3$ with $20$ ways to make $a=21$.
Now you can see a pattern right? So far our sum is $1*23+2*20$. Let's continue this pattern on, because we can see a pattern in our cases $(2,24),(3,21),(4,18),(5,15),(6,12),(7,9),(8,6),(9,3)$.
Thus, we get a sum of $1*23+2*20+3*17+4*14+5*11+6*8+7*5+8*2 = 324$ solutions.
EDIT: I notice that some other people are including $0$ as a natural number, so here's a revised solution. Since we can have both $x$ be $0$, or one $x$ be $0$ ,that means we may have $a,b = 0 or 1$. Thus, our new cases are $(0,30),(1,27)(2,24),(3,21),(4,18),(5,15),(6,12),(7,9),(8,6),(9,3),(10,0)$. Also, before for case $(2,24)$, we had $1$ way to make $a=2$ using $(1,1)$. However, now that we can use $0$, we add $2$ pairs to get $(1,1),(2,0),(0,2)$. Similar logic can be used to add $2$ pairs to all ways to make $a,b$. Now, let's find our new sum.
For case $(0,30)$ we can have $a=0$ with $(0,0)$ and $b=30$ with $(0,30)$ through $(30,0)$ or $31$ pairs. Thus, the number of ways for this case is $1*31$.
For case $(1,27)$ we can have $a=1$ with $(0,1),(1,0)$ and $b=27$ with $(0,27)$ through $(27,0)$ or $28$ pairs. So we have $2*28$ total ways for this case.
Now that we have the base cases $1*31$ & $2*28$,we may use the logic we used previously to get our sum of $1*31+2*28+3*25+4*22+5*19+6*16+7*13+8*10+9*7+10*4+11*1 = 726$
$x_3\equiv x_4 \equiv 0 \pmod{3}$
$x_3 \equiv 1 \pmod{3}$ and $ x_4 \equiv 2 \pmod{3}$
$x_3 \equiv 2 \pmod{3}$ and $ x_4 \equiv 1 \pmod{3}$.