Dear Sarah, first of all, you may cancel the factor of $\pi$ on both sides.
Second, $\exp(ix)=\cos(x)+i\sin(x)$ and
$$\cos(\pi/3)=\frac 12, \quad \sin(\pi/3) = \frac{\sqrt{3}}{2}, \quad e^{i\pi} = -1$$
so
$$e^{i\pi/3} - e^{i\pi} = \frac 12 + i \frac{\sqrt{3}}{2} + 1 = \frac 32 + i\frac{\sqrt{3}}{2} = \frac{1}{2} (3 +\sqrt{3}) $$
just like you wrote. If you need it, $\cos(\pi/3)$ is $\cos (60°)$ - thanks, Hans - which is equal to $1/2$ because of a simple picture of an equilateral triangle. $\sin(\pi/3)$ is calculated via $\sin^2x+\cos^2 x = 1$. For a derivation of the exponential of an imaginary number in terms of cosines and sines, see e.g.
Complex Exponents