Let's define $H^{n} = \left\lbrace x \in \mathbb{R}^{n} : x_n \geq 0 \right\rbrace$
Trying to answer my own question on why "the boundary of the boundary of a manifold is empty", here I don't know how to conclude that the boundary is empty :
By restriction of chart I have parametrized a manifold, which is $\partial M$, with open sets of $\mathbb{R}^{n-1}$, those open are infact $U \cap \partial H^{n}$; I'd like to state that the manifold has boundary simply from this arguing by contraddiction : if it has boundary, I could find at the same time a neighborhood of a point $p \in \partial \partial M$ which is diffeomorphic to some $U \cap \partial H^{n}$ open in $\partial H^{n}$ with the endowed topology (as point of $\partial M$) and to some $U' \cap \partial H^{n-1}$, open in $\partial H^{n-1}$ with the endowed topology (as point of $\partial \partial M$) as well.
I don't how to conclude from here since it should be true that such open can't be diffeomorphic, they shouldn't be even homeomorphic, unless that the open $U \cap \partial H^{n}$ lies in $\left\lbrace x_{n-1} = 0\right\rbrace$ too. This should generate a contradiction which I'm unable to see or state, but I feel like that at that point $U \cap \partial H^n$ won't be open in $\partial H^n$ anymore.
Any help on how to formalize the senteces above would be appreciated, feels necessary to me given the freedom which the boundary has been defined, otherwise I could have just simply stopped to "the boundary has been parametrized with open sets of $\mathbb{R}^{n-1}$", but if this is true, it should be also follow that $U \cap \partial H^n$ can't lie entirely in $\left\lbrace x_i = 0\right\rbrace$, right ?