Normally, one proves that two normed linear spaces are isometric in a constructive™ way, by exhibiting an isometry between them. One common exception: since it's widely known that any two separable Hilbert spaces are isometrically isomorphic to each other, an explicit isometry is unnecessary in this case.
One elementary way to show that two spaces $X,Y$ are not isometrically isomorphic is to find a subset of $X$ that cannot be isometrically embedded into $Y$. For example, consider the subset $$A=\{(\pm 1,0), (0,\pm 1)\}\subset (\mathbb R^2,\|\cdot \|_1)$$
Any two points of $A$ are at distance $2$ from each other. Such a configuration is impossible in $(\mathbb R^2,\|\cdot \|_2)$. Indeed, three points at distance $2$ from one another must lie at the vertices of an equilateral triangle, and there is nowhere to put the fourth one.