In second countable topology(i.e. has countable bases), obviously all open sets are countable union of base elements. But the inverse seems not true.
The sorgenfrey line $R_l$ seems to be an example. The proof is analogous to sorgenfrey line is lindelof and sorgenfrey line is T6 perfectly normal. Given an open set $U = \bigcup B_\alpha$ for some base elements $B_\alpha \in \mathcal{B}$, partition it into its interior $I$ in the ordinary topology $R$ and $U-I$. Because $R_l$ is finer than the ordinary topology $R$ and $R$ is second countable, $I$ can be written as countable union of base elements both in $R$ and $R_l$ i.e. $I=\bigcup_i (c_i,d_i)$. For $U-I$, each $x \in U-I$ has to belong to a base element $[x, b_x) \subset U$ otherwise if $x \in (a,b) \subset U$, it will be in $I$. Replace $b_x$ with a rational number $b'_x$ by shrinking. For two distinct point $x, y \in U-I$, $[x,b'_x)$ and $[y,b'_y)$ have to be disjoint, otherwise either $x$ or $y$ will be in $I$. Therefore, the elements in $U-I$ is countable. Now, $U = I\bigcup (U-I) = \bigcup_i (c_i, d_i) \bigcup (\bigcup_{x\in U-I} [x, b'_x))$. Hence, all open sets in $R_l$ is countable union of base elements. However, $R_l$ is not second countable.
Is my proof correct roughly? And I would like more examples of topologies that are not second countable, but in which every open sets are countable union of base elements.
Edit: as the comments mentioned, there is a trivial example that if all open sets are considered base elements, every topology has this property. I think to eliminate this triviality, the original question should be reformulated as
For every possible collections of bases, all open sets can be written as countable union of bases in this topology, yet the topology is not second countable.
Clearly, $R_l$ is still valid as an example.