Alright... I have a usually rant about how $\mod m$ doesn't actually mean the remainder function and... well, I get tired of ranting.
I'm going to write what you mean by $a\mod b$ as $a \% b$ because .... reasons....
Anyway:
Claim: If $b|c$ then $(a\% c) \% b = a\% b$.
Proof: Let $a\% c = r$. Let $r\%b = s$. Now $b|c$ so let $c = kb$.
Then $a = mc + r$ for some $m$ and $r = nb + s$ for some $n$. ANd so $a=mc + r = (mk)b+(nb+s)=(mk+n)b + s$.
So $a\%b = s = (a\%c)\%b$.
Now to your issue at hand:
What is $n \%b^{k+1}- (n\% b^{k+1})\%b^{k}$?
Okay $n$ is and integer and suppose $n = A\times b^k + R$ where $0\le R < b^k$. And suppose $A = M\times b + s$ where $0 \le s < b$, then
$n = M\times b^{k+1} + s \times b^k + R$.
So $n \%b^{k+1} = s\times b^k + R$.
And $n \%b^k = R$. So
$n \%b^{k+1}- (n\% b^{k+1})\%b^{k}=( s\times b^k + R) =s\times b^k$.
Which I think is what you where expecting. $s$ is the $k$th place digit and we have the $k$th place digit times $b^k$.
Is there a formula for finding the $k$th digit? Well, what we just did. Or we could make up any notation we want.
$n\% b^{k+1} - (n\%b^{k+1})\% b^{k} = n\%b^{k+1} - n\%b^{k} = (\text{the kth digit of } n)\times b^k$.