I did not look at the earlier answer or the linked post, so this will be written in completely independent terms, so hopefully avoid whatever the source of confusion was. Apologies if I just end up regurgitating the previous explanations.
Given any $\alpha\in \bar{\mathbb{Q}}$, let $\beta_1,\cdots \beta_k$ be its conjugates (including itself). In other words $$\prod_{i=1}^k (x-\beta_i)$$ is the minimal polynomial of $\alpha$ over $\mathbb{Q}$.
Then $$\prod_{i=1}^k (\alpha\otimes 1-1\otimes\beta_i)=0,$$
as symmetric polynomials expressions in the $\beta_i$ are rational (they are the coefficients of the minimal polynomial of $\alpha)$ , so slip across the tensor product once the above expression is multiplied out.
Thus if $p\subseteq \bar{\mathbb{Q}}\otimes_{\mathbb{Q}}\bar{\mathbb{Q}}$ is prime, then for each $\alpha\in \bar{\mathbb{Q}}$, the prime $p$ must contain $$\alpha\otimes 1-1\otimes\beta,$$ for some conjugate $\beta$ of $\alpha$.
Thus in the quotient $(\bar{\mathbb{Q}}\otimes_{\mathbb{Q}}\bar{\mathbb{Q}})/p$ we must have for any $\alpha,\gamma\in \bar{\mathbb{Q}}$:
\begin{eqnarray*}\alpha\otimes \gamma&=&(\alpha\otimes 1)(1\otimes \gamma)\\&=&(1\otimes \beta)(1\otimes\gamma)\\&=&(1\otimes \beta\gamma),\end{eqnarray*}
where $\beta$ is some conjugate of $\alpha$.
That is $(\bar{\mathbb{Q}}\otimes_{\mathbb{Q}}\bar{\mathbb{Q}})/p$ is a quotient of $\bar{\mathbb{Q}}$, hence isomorphic to $\bar{\mathbb{Q}}$. In particular the answer to your first question is yes: $\bar{\mathbb{Q}}$ is a field, so $p$ must be maximal.
In answer to your second question, the prime ideals of $\bar{\mathbb{Q}}\otimes_{\mathbb{Q}}\bar{\mathbb{Q}}$ are precisely the kernels of ring homomorphisms $\bar{\mathbb{Q}}\otimes_{\mathbb{Q}}\bar{\mathbb{Q}}\to \bar{\mathbb{Q}}$, mapping $\alpha\otimes \gamma \mapsto \beta\gamma$ as above.
Note these restrict to the identity on the second factor.
In particular, if $f\colon \bar{\mathbb{Q}}\otimes_{\mathbb{Q}}\bar{\mathbb{Q}}\to\bar{\mathbb{Q}}$ is such a ring homomorphism, then pre-composing with the inclusion: $$\bar{\mathbb{Q}}\to\bar{\mathbb{Q}}\otimes_{\mathbb{Q}}\bar{\mathbb{Q}},$$
mapping $\alpha\mapsto \alpha\otimes 1$, we get a field automorphism $g\colon\bar{\mathbb{Q}}\to \bar{\mathbb{Q}}$.
Given $g\in$Gal$(\bar{\mathbb{Q}} /\mathbb{Q})$, we have a prime ideal $p_g$ given by the kernel of the map $\bar{\mathbb{Q}}\otimes \bar{\mathbb{Q}}\to \bar{\mathbb{Q}}$, sending:
$$(\alpha\otimes\beta)\to g(\alpha)\beta,$$
and we have shown that every prime ideal has this form.
Finally note that given $g,g'\in$Gal$(\bar{\mathbb{Q}} /\mathbb{Q})$, if for some $\alpha\in \bar{\mathbb{Q}}$ we have $g(\alpha)\neq g'(\alpha)$, then $$
\alpha\otimes1-1\otimes g(\alpha)\in p_g,\qquad \alpha\otimes1-1\otimes g'(\alpha)\in p_{g'}.$$
As $1\otimes(g(\alpha)-g'(\alpha))$ is a unit, we may conclude that $p_g\neq p_{g'}$.
Thus we may conclude that the prime ideals of $\bar{\mathbb{Q}}\otimes \bar{\mathbb{Q}}$ are in one to one correspondence with
${\rm Gal}(\bar{\mathbb{Q}} /\mathbb{Q})$.