The answer to your first question is yes, dominated convergence can be used to justified the change of order of integration and differentiation in Complex analysis; however, in the setting you described it is an overkill since you are integrating over piecewise differentiable maps, and there are Calculus theorems (see Tom Apostol's Analysis in the section about Riemann integration) that can handle the change of order of differentiation and integration in your setting.
In ant event, what you are attempting do, you are missing what the limiting process is: For a fixed $z_0$, one should try to dominate $\frac{1}{z-z_0}\Big(\frac{f(\gamma(t)}{\gamma(t)-z}-\frac{f(\gamma(t)}{\gamma(t)-z_0)}\Big)\gamma'(t)$ in a neighborhood of of $z_0$.
In attempting to clarify the issues with your attempt, I will present some instances where Lebesgue integration is a great tool to solve Complex variable problems with three examples, which I believe, will illustrate that one may have to go beyond Calculus tools. To achieve that I consider only three. The first is slightly more than what you asked; the second one deals with what you asked; the third is to try to show how Lebesgue integration can be used to give an extension of Cauchy's theorem and estimates.
Example 1:
Let $\mu$ be a complex measure on a measurable space
$(X,\mathscr{B})$ and let $D\subset\mathbb{C}$ be open. Suppose $\varphi$
is a bounded complex valued function in $D\times X$ such that
$\varphi(\cdot,x)$ is holomorphic in $D$ for each $x\in X$, and that
$\varphi(z,\cdot)$ is $\mathscr{B}$--measurable for each $z\in D$. Define
$$
f(z):=\int_X \varphi(z,x)\mu(dx),\qquad z\in D.
$$
Then $f$ is holomorphic in $D$.
There are several ways to go about this. Here is one that makes use of Cauchy's theorem along with dominated convergence.
The conditions of the statement above imply that for $z\in D$ fixed
$$\partial_z\varphi(z,x)=\lim_{w\rightarrow z}\frac{\varphi(w,x)-\varphi(z,x)}{w-z}$$
is measurable in $x$.
Let $M:=\sup_{(z,x)\in D\times X}|\varphi(z,t)|$. For $z_0\in D$, choose $r>0$ small enough so that the closed ball $\overline{B(z_0;2r)}\subset D$. For any $z\in B(z_0;r)$,
$$
\begin{align}
\frac{\varphi(z,x)-\varphi(z_0,x)}{z-z_0}&=\frac{1}{z-z_0}\frac{1}{2\pi i}\int_\gamma\Big(\frac{\varphi(\xi,x)}{\xi-z}-\frac{\varphi(\xi,x)}{\xi-z_0}\Big)\,d\xi\\
&=\frac{1}{2\pi i}\int_\gamma\frac{\varphi(\xi,x)}{(\xi-z)(\xi-z_0)}\,d\xi
\end{align}
$$
where $\gamma$ is the path $\gamma(t)=z_0+2re^{it}$, $0\leq t\leq 2\pi$. Then
$$
\begin{align}
\Big|\frac{\varphi(z,x)-\varphi(z_0,x)}{z-z_0}\Big|&=\frac{1}{2\pi}\left|\int^{2\pi}_0\frac{\varphi(z_0+2r e^{it},x)}{(z-z_0-2re^{it})2r e^{it}}i2r e^{it}\,dt\right|\leq \frac{M}{r}
\end{align}
$$
since $|z-z_0-2r e^{it}|\geq r$. Being a complex measure, $|\mu|(X)<\infty$ and so, we can apply dominated convergence to obtain first that $x\mapsto \partial_z\varphi(z_0,x)$ is integrable with respect to $\mu$ (with respect to $|\mu|$ rather, which in terns implies integrability with resect to positive and negative parts of the real and imaginary parts of $\mu$), and second that
$$
\begin{align}
\lim_{z\rightarrow z_0}\frac{f(z)-f(z_0)}{z-z_0}&=\lim_{z\rightarrow z_0}\int_X \frac{\varphi(z,x)-\varphi(z_0,x)}{z-z_0}\,\mu(dx)\\
&=\int_X \lim_{z\rightarrow z_0}\frac{\varphi(z,x)-\varphi(z_0,x)}{z-z_0}\,\mu(dx)=\int_X\partial_z\varphi(z,x)\,\mu(dx)
\end{align}
$$
Comment:
Dominated convergence for the complex measure $\mu$ can be understood in the sense that dominated convergence is being applied with respect to the positive and negative parts of the real and imaginary parts of $\mu$. Alternatively, one can consider the variation measure $|\mu|$ of $\mu$ and apply dominated convergence with respect to $|\mu|$; this will imply dominated convergence with respect t the positive and negative parts of the real and imaginary parts of $\mu$.
The machinery from Lebesgue integration theory can be used along with classical complex analysis results to solve many problems in complex analysis. In Example 1 for instance we can furnish another solution, which is much more elegant, by apply Morera's theorem (integration over triangles) together with Fubini's theorem to obtain that $f$ is holomorphic in $D$. I leave the details to you.
Example 2:. For simplicity, suppose $f$ is analytic in an open convex set $D$. Cauchy's theorem (in a convex set) states that for any closed path $\gamma$ in $D$
$$
f(z)\operatorname{Ind}_\gamma(z)=\frac{1}{2\pi i}\int_\gamma \frac{f(\xi)}{\xi -z}\,d\xi
$$
where $z\in D\setminus\gamma^*$ ($\gamma^*$ is the range in $\mathbb{C}$ of the the path $\gamma$). All that can be proved without resorting to Lebesgue integration of course. In any event, suppose $\gamma$ is the path and $\gamma(x)= z_0+ Re^{ix}$, $0\leq x\leq 2\pi$. We can apply the result of Example 1 with $\varphi: B(0;R/2)\times[0,2\pi]\rightarrow\mathbb{C}$ given by
$$
\varphi(z,x)=\frac{f(z_0+R e^{xi})}{\gamma(x)-z}
$$
and
$$
\mu(dx)=\frac{1}{2\pi i}\gamma'(x)\,dx
$$
since
$$|\phi(z,x)|\leq 2\frac{\sup_{w:|w-z_0|=R}|f(w)|}{R}=M<\infty$$
All this gives you
$$
f'(z)=\frac{1}{2\pi i}\int_\gamma \frac{f(\xi)}{(\xi -z)^2}\,d\xi
$$
Example 3:
Let $\mu$ be a complex measure on a measurable space
$(\Omega,\mathscr{F})$ and let $\varphi$ be a complex--valued measurable
function on $\Omega$. Suppose $D\subset\mathbb{C}$ is an open set
which does not intersect $\varphi(\Omega)$.
Then, the map
$f:D\rightarrow\mathbb{C}$ given by
$$
\begin{align}
f(z)= \int_\Omega\frac{\mu(d\omega)}{\varphi(\omega)-z}\tag{1}\label{one}
\end{align}
$$
is analytic. Moreover, if the closed ball $\overline{B}(a;r)\subset D$, then
$$
\begin{align}
f(z)=\sum^\infty_{n=0}c_n(z-a)^n,\qquad z\in B(a;r)\tag{2}\label{two}
\end{align}
$$
where
$$
\begin{align}
c_n=\int_\Omega\frac{\mu(d\omega)}{(\varphi(\omega)-a)^{n+1}},\qquad
|c_n|\leq \frac{\|\mu\|_{TV}}{r^{n+1}},\qquad n\in\mathbb{Z}_+.\tag{3}\label{three}
\end{align}
$$
If $R$ is the radius of convergence of $\eqref{two}$, then $r\leq R$.
Here is a short proof to illustrate how dominated convergence may be used (see also notes at the bottom of this answer).
If $\overline{B}(a;r)\subset D$, then
$q:=\inf_{\omega\in\Omega}|\varphi(\omega)-a|>r$, and so
$$
\begin{align}
\frac{|z-a|}{|\phi(\omega)-a|}\leq \frac{|z-a|}{q}\leq\frac{r}{q}<1,\qquad
\omega\in\Omega,\quad z\in B(a;r).
\end{align}
$$
Hence, for any $z\in B(a;r)$ fixed, the series
$$
\omega\mapsto
\sum^\infty_{n=0}\frac{(z-a)^n}{(\varphi(\omega)-a)^{n+1}}
=\frac{1}{\varphi(\omega)-z}
$$
converges absolutely and uniformly in $\Omega$. By dominated convergence (to justify change of order of summation and integration)
$$
f(z)=\int_\Omega \frac{\mu(d\omega)}{\varphi(\omega)-z}=
\int_\Omega \sum^\infty_{n=0}\frac{(z-a)^n}{(\varphi(\omega)-a)^{n+1}}
\,\mu(d\omega)
= \sum^\infty_{n=0}c_n(z-a)^n,
$$
where the $c_n$ satisfy $\eqref{three}$. The last statement follows from the estimate
$$\begin{align}
\limsup_{n\rightarrow\infty}\sqrt[n]{|c_n|}\leq\lim_{n\rightarrow\infty}\frac{1}{r}\sqrt[n]{\frac{\|\mu\|_{TV}}{r}}=\frac{1}{r}
\end{align}
$$
Notes:
Examples 1 and 2 cover the typical situation of integration along paths. In such cases you may consider the complex measure $\mu(dt)=\gamma'(t)\,dt$ where $\gamma:[a,b]\rightarrow\mathbb{C}$ is a piecewise differentiable function.
Example 3 is reminiscent of Cauchy's estimates.