How do we meaningfully calculate $i^i$? One way which comes to mind is to write
$i = e^{\pi i \ 2}, \tag 1$
and thus
$i^i = (e^{\pi i / 2})^i; \tag 2$
if we now assume the rule
$(a^b)^c = a^{bc}, \; a, b, c \in \Bbb C, \tag 3$
is valid, then (2) becomes
$i^i = (e^{\pi i / 2})^i = e^{\pi i^2 / 2} = e^{-\pi / 2}. \tag 4$
So far, so good; however, the equation (1) does not uniquely define $i$ as an exponential; indeed, we have
$i = e^{(2n + 1/ 2)\pi i}, \; n \in \Bbb Z, \tag 5$
whence
$i^i = (e^{(2n + 1/2)\pi i})^i = e^{(2n + 1/2)\pi i^2} = e^{-(2n + 1/2)\pi}, n \in \Bbb Z. \tag 6$
If we accept these results, we may move on to attempting to calculate $i^j$; from (5), assuming (3) holds for quaternions,
$i^j = (e^{(2n + 1/2)\pi i})^j = e^{(2n + 1/2)\pi ij} = e^{(2n + 1/2)\pi k}$
$= e^{2n\pi k} e^{\pi k / 2} = e^{\pi k / 2} = k, \; n \in \Bbb Z. \tag 7$
It is perhaps worth noting that
$i^j = k = ij, \tag 8$
and that via cyclic permutation $i \to j \to k$ we find
$j^k = i = jk, \tag 9$
and
$k^i = j = ki. \tag{10}$
Note Added in Edit, Friday 19 June 2020 12:51 PM PST: A few words in response to the comment of Konstantin Konstantinov on this answer. The defining relations of the quaternion algebra,
$i^2 = j^2 = k^2 = -1, \tag{11}$
$ij = k, jk = i, ki = j, \tag{12}$
found in this wikipedia entry, lead naturally to the formulas
$e^{2n\pi i} = e^{2n \pi j} = e^{2n\pi k} = 1, n \in \Bbb Z, \tag{13}$
from which we see that for
$t \in [0, 2\pi) \tag{14}$
$e^{(2n\pi + t)i} = e^{2n\pi i}e^{t\pi i} = e^{t\pi i}, n \in \Bbb Z, \tag{15}$
and corresponding formulas with $j$ and $k$ replacing $i$. From this we see that there are a countably infinite number of distinct solutions to (15), viz.
$2n\pi + t, \; n \in \Bbb Z, \tag{16}$
with corresponding solution sets for the $j$ and $k$ variants of (15). We further observe that
$e^{i \theta} = \cos \theta + i \sin \theta, \tag{17}$
again with the corresponding relations for $j$ and $k$; of course (17) gives rise to (5) in the usual manner:
$e^{(2n + 1/ 2)\pi i} = \cos ((2n + 1/2)\pi) + i \sin ((2n + 1/2)\pi)$
$= i\sin((2n + 1/2)\pi) = i\sin((1/2) \pi) = i, \; n \in \Bbb Z, \tag{18}$
and again, the corresponding statements hold for $j$ and $k$.
End of Note.