The quadratic formula works very well in any non-characteristic-$2$ field. So the roots of your $x^2+3x+3$ are
$$
\frac{-3\pm \sqrt{3^2 - 4\cdot 1\cdot 3}}{2\cdot 1} = 1\pm3\sqrt2
$$
Since $\Bbb F_{25}$ is a quadratic extension of $\Bbb F_5$, it contains all the square roots of any element in $\Bbb F_5$. So $\sqrt 2$ actually exists in $\Bbb F_{25}$, and your polynomial has roots. In fact, we get that any quadratic polynomial over $\Bbb F_5$ has roots in $\Bbb F_{25}$. So in order to find irreducible quadratics, you need to use at least one of the twenty non-$\Bbb F_5$ elements of $\Bbb F_{25}$.
For instance, we could take $x^2 + \sqrt2$. There is no square root to $\sqrt2$ in $\Bbb F_{25}$ (proof below), so this is irreducible.
All elements in $\Bbb F_{25}$ may be written in a unique way as $a + b\sqrt2$, where $a, b\in \Bbb F_5$. If $\sqrt2$ has a square root in $\Bbb F_{25}$, then we have a solution to
$$
(a + b\sqrt2)^2 = \sqrt2\\
a^2 + 2b^2 + 2ab\sqrt2 = \sqrt2\\
a^2 + 2b^2 = 0\quad\land\quad 2ab = 1
$$
The only solution in $\Bbb F_5$ to $a^2 + 2b^2 = 0$ is $a = b = 0$, but that doesn't solve $2ab = 1$, so $\sqrt{\sqrt2}$ doesn't exist in $\Bbb F_{25}$.