Elements of quotient are classes of equivalence (some subsets) of original ring.
If we take $\mathbb Z / 6\mathbb Z$, elements are equal if they differ by exactly $6$ (there difference is in $6\mathbb Z$). So elements of quotient rings are sets:
0) $\{0, 6, -6, 12, -12, 18, -18, \ldots\} = 0 + 6\mathbb Z$
1) $\{1, 7, -5, 13, -11, 19, -17, \ldots\} = 1 + 6\mathbb Z$
2) $\{2, 8, -4, 14, -10, 20, -16, \ldots\} = 2 + 6\mathbb Z$
and so on.
To take, for example, sum of such elements, we need to sum elements of it member-wise:
$$(1 + 6\mathbb Z) + (2 + 6\mathbb Z) = \{1, 7, -5, \ldots\} + \{2, 8, -4, \ldots\} = \{3, 9, -3, 9, 15, 3, -3, 3, -9, \ldots\} = 3 + \mathbb Z$$
($6\mathbb Z$ been ideal guarantees that member-wise sum or product of two equivalence classes is also an equivalence class)