Let $f(a,b)=\arcsin(a)+\arcsin(b)$. We assume in our analysis that $0\le a\le 1$ and $0\le b\le 1$. Analysis for $a$ and $b$ in the other quadrants are left as exercises.
We wish to restrict $f(a,b)$ such that $0\le f(a,b)\le \pi/2$. That is, $f(a,b)=\arcsin(x)$ for some $x\in [0,1]$.
First note that the arcsine function increases monotonically. Hence, $f(a,b)=\arcsin(a)+\arcsin(b)$ increases in each of its arguments $a$ and $b$.
ASIDE: Use of Calculus to Show that $\arcsin(x)$ Increases Monotonically
One way to see that $f(a,b)$ increases monotonically in $a$ and $b$ to note its first partial derivatives given by
$$\frac{\partial f(a,b)}{\partial a}=\frac1{\sqrt{1-a^2}}\\\\
\frac{\partial f(a,b)}{\partial b}=\frac1{\sqrt{1-b^2}}$$
are strictly positive.
Next, note that $\sin(f(a,b))=a\sqrt{1-b^2}+b\sqrt{1-a^2}$. Inasmuch as the value of the sine function cannot exceed $1$, the maximum value of $a\sqrt{1-b^2}+b\sqrt{1-a^2}$ is $1$.
It is straightforward to show that the locus of points for which $a\sqrt{1-b^2}+b\sqrt{1-a^2}=1$ is given by the set $\{(a,b)|a^2+b^2=1\}$.
ASIDE: Use of Calculus to Find Where $\sin(f(a,b))$ Is a Maximum Value
As easy way to show that $\sin(f(a,b))=1$ when $a^2+b^2=1$ is to set its first partial derivatives, given by
$$\frac{\partial \sin(f(a,b))}{\partial a}=\sqrt{1-b^2}-\frac{ab}{\sqrt{1-a^2}}\\\\
\frac{\partial \sin(f(a,b))}{\partial b}=\sqrt{1-a^2}-\frac{ab}{\sqrt{1-b^2}}$$
to $0$ and solve the resulting equations.
So, we now have found that $\sin(f(a,b))$ has its maximum value on the circle $a^2+b^2=1$ for which $\sin(f(a,b))=1$. Therefore, $f(a,b)=\pi/2$ on the circle $a^2+b^2=1$.
Inasmuch as $f(a,b)$ is increasing in both $a$ and $b$, we find that $f(a,b)>\pi/2$ when $a^2+b^2>1$. Hence, the solution space is given by
$$a^2+b^2\le 1$$
for $a\in[0,1]$ and $b\in [0,1]$.