Additional counterexamples can be found in functional analysis. Let $X$ be a (real or complex) Banach space, and let $\mathcal T_{\text{norm}}$ denote the norm topology on $X$. If $X$ is infinite-dimensional, then there exist linear topologies $\mathcal T$ on $X$ that are complete and strictly finer than $\mathcal T_{\text{norm}}$, for example:
- One may take $\mathcal T$ to be the finest locally convex topology on $X$ — see [Sch99, p. 56, example before 6.3].
- For additional examples, see this answer on MathOverflow.
Such a topology $\mathcal T$ can never be metrizable, for otherwise it would follow from the open mapping theorem (cf. [Rud91, Corollary 2.12(d)]) that $\mathcal T = \mathcal T_{\text{norm}}$.
Added later: you don't even need the open mapping theorem for this — it can be shown by elementary means that the finest locally convex topology on an infinite-dimensional vector space is never metrizable (see the answers to this question).
Every infinite-dimensional vector space admits a norm (see here), and can therefore be equipped with two locally convex topologies $\mathcal T_{\text{norm}} \subset \mathcal T_{\text{finest lc}}$, where $\mathcal T_{\text{norm}}$ is metrizable but $\mathcal T_{\text{finest lc}}$ is not.
References.
[Rud91]: Walter Rudin, Functional Analysis, Second Edition (1991), McGraw–Hill.
[Sch99]: H.H. Schaefer, M.P. Wolff (translator), Topological Vector Spaces, Second Edition (1999), Graduate Texts in Mathematics 3, Springer.