Just an example.
The square roots of $-3 \equiv 4 \pmod 7$ are $\pm 2 \pmod 7.$
The square roots of $-3 \equiv 36 \pmod{13}$ are $\pm 6 \pmod{13}$
By the Chinese Remainder Theorem, one of the pairs comes from $19,$ because $$ 19 = 3 \cdot 7 - 2 = 13 + 6.$$ That pair, $\pm 19 \pmod {91}$ are
$$ 19, 72 \pmod{91} $$ So we are naming $a = 19.$
The other pair comes from $33,$ because $$ 33 = 5 \cdot 7 - 2 = 3 \cdot 13 - 6.$$ That pair, $\pm 33 \pmod {91}$ are
$$ 33, 58 \pmod{91} $$ So we are naming $b = 33.$
Then $p=7, \; \; $ $q = 13.$
Let's see, $33-19 = 14$ is a multiple of $7,$ so $a \equiv b \pmod 7.$
Finally, $33+19 = 52$ is a multiple of $13$ so $a+b \equiv 0 \pmod {13} \; , \; \; $ also written $a \equiv -b \pmod {13}.$