If the sequence $z_0 = 1, z_{n+1}= \exp \frac{\pi}{2} z_n$ converges to some $\zeta\in \mathbb{C}$, then it converges to a point with $\zeta = \exp \frac{\pi}{2} \zeta$, and $\zeta = i$ is a solution of the latter equation. (The expression in the title doesn't quite make sense without some initial condition like $z_0 = 1$). The sequence $(z_n)$ doesn't converge, though; we have $z_{n+1} > 2z_n$ for (e.g.) real $z_n \geq 1$.
A simpler example of the same phenomenon is the sequence $z_0 = 2, z_{n+1} = z_n^2 + z_n + 1$. In the notation above, we would have $\zeta = i$. The sequence $z_n$ doesn't converge to $i$, though; the $z_n$ are real with $z_{n+1} > 2^n$ for all $n$, and $z_n \to\infty$ monotonically as $n\to\infty$.