A common misconception I've run across is to conflate the conjugate space $\overline V$ with $V$ in too strong a fashion. I will attempt to describe what I mean by this below. (Disclaimer: I am not a complex geometer. Far from it. This answer is just sharing what I have understood from attempts to resolve my previous and lasting confusions. ;-;)
a) For a complex vector space $(V,+,\cdot)$, the conjugate space $\big(\overline V,+,\star\big)$ is defined to have the same underlying set and additive structure, but scalar multiplication is conjugated: $\lambda \star v=\bar\lambda\cdot v.$ Since $V$ and $\overline V$ have the same dimension, there is a $\mathbb C$-linear isomorphism $V\cong \overline V,$ but it is not canonical. The $\mathbb C$-linear isomorphisms $V\cong \overline V$ are in natural bijection with $\mathbb C$-antilinear bijections $V\rightarrow V$ (which does not include $\text{Id}_V$).
b) Now what is a real structure on $V$? There are several ways to look at it, but one is as a $\mathbb C$-antilinear involution $\varphi:V\rightarrow V.$ That means that it has the extra condition that $\varphi^2=\text{Id}_V$, which is stricter than just having some $\mathbb C$-antilinear bijection $V\rightarrow V$. Thus identifying the space $V$ with its conjugation $\overline V$ is a strictly weaker notion than choosing a real structure on $V$.
To see this in action, check out this question that I had a while back. Constructions tend to only work on bundles if you can do them canonically (perhaps up to homotopy), because otherwise things may twist up and clash globally. The answer to the linked question gives a complex vector bundle that is isomorphic to its conjugate bundle, but is not a complexification of a real vector bundle. In other words, you can do (a) globally, but you can't do (b) globally.
This "weakness" isn't to say that conjugate vector spaces aren't useful; in fact, they will probably occur far more than real structures in your reading of Huybrechts. For example, everything that you do in terms of $(p,q)$-forms is based on a decomposition $V\otimes_{\mathbb R}\mathbb C\cong V\oplus \overline V$.
Update: Here's another "false resemblance." A real structure on a $\mathbb C$-vector space $(V,J)$ is a way of identifying $V$ as the complexification of an $\mathbb R$-vector space. But what if we complexify something that already has a complex structure? By this, I mean that we form $(V_\mathbb{R})^\mathbb{C}=V\otimes_\mathbb{R}\mathbb C$. We can write this as $V\otimes_\mathbb{R}\mathbb C=V\oplus iV$ or $V\otimes_\mathbb{R}\mathbb C=V\oplus \overline V$. This seems to imply that we can identify $iV$ and $\overline V$, but this is not the case. If we are careful, we actually see that the two copies of $V$ are different:
In the decomposition $V\otimes_\mathbb{R}\mathbb C=V\oplus iV$, we embed $V\hookrightarrow V\otimes_\mathbb{R}\mathbb C$ and $iV\hookrightarrow V\otimes_\mathbb{R}\mathbb C$ by the maps $v\mapsto v\otimes 1$ and $v\mapsto v\otimes i$, respectively. This "remembers" how $V\otimes_\mathbb{R}\mathbb C$ was formed as a complexification, but it doesn't make $J$ and $i$ work in a particularly compatible way. Note that $V$ and $iV$ are both closed under $J$, but they are interchanged when we multiply by $i$. Thus, we have two complex structures, but these are only complex subspaces with respect to one.
In the decomposition $V\otimes_\mathbb{R}\mathbb C=V\oplus \overline V$, we embed $V\hookrightarrow V\otimes_\mathbb{R}\mathbb C$ and $\overline V\hookrightarrow V\otimes_\mathbb{R}\mathbb C$ by the maps $v\mapsto v\otimes 1-Jv\otimes i$ and $v\mapsto v\otimes 1+Jv\otimes i$, respectively. This is different from the above, although perhaps not super enlightening. More useful is the description $$V=\{w\in V\otimes_\mathbb{R}\mathbb C:Jv=iv\}\quad\text{and}\quad \overline V=\{w\in V\otimes_\mathbb{R}\mathbb C:Jv=-iv\}.$$ This shows us that $V$ and $\overline V$ are complex subspaces under both complex structures. These two structures are equal on $V$ and opposite on $\overline V,$ which allows us to talk about "holomorphic" and "anti-holomorphic" things on a complex (or almost complex) manifold.