$$\mathbb{Z}_+ \cup \{ -1 + \frac{1}{2}, -2+\frac{1}{3}, -3+\frac{1}{4}, -5+\frac{1}{6}, \cdots \}$$ Is apparently an example because $0$ is not in $S + S$. I am unclear as to why it is not though.
$Edit$: I am the user that originally posted this question (I should have made an account) but I realized I am not sure why S itself is closed either. Isn't zero a boundary point of S not contained in S?