If it was a smooth manifold, it would be a submanifold of the plane and hence any point of the triangle, and in particular any vertex, would have a neighbourhood $V$, that, in some basis of the plane could be written $V= \{ (x,f(x)) \ , x \in (-1,1) \}$ where $f:(-1,1) \to \Bbb R$ is a smooth map and $(0,f(0))$ is the coordinates of the vertex in the chosen basis of the plane.
But such an $f$ cannot be smooth because it would also have to be piecewise linear.
Edit: There are many equivalent definitions of a submanifold of $\Bbb R^n$, I used one of them, you can find it here at (d) in proposition 3.2.1. When working with subsets of $\Bbb R^n$, it is often better to use one of these caracterisations instead of just charts, because it simplifies thing so much.
So if your triangle was a smooth submanifold of $\Bbb R^2$ it should be locally parametrized by a smooth function, and this is not the case at a vertex, since the only parametrizations are piecewise linear, and henceforth not smooth.
But note that it depends essentially on the fact that your triangle is a subset of $\Bbb R^2$: it inherits the topology of the plane but cannot inherit the differentiable structure because of the "corner". You can find much more details in here (the accepted answer and the comments under it should really help you out).