I assume you mean metrizability of the unit ball in the dual space. Since you don't ask about compactness, we can cheat and assume Alaoglu's theorem that the unit ball is compact in the weak*-topology. Since a continuous injective map from a compact space to a Hausdorff space is a homeomorphism onto its image, it suffices to find a continuous and injective map into some metrizable space.
Choose a dense sequence $\langle x_n : n \in \mathbb{N}\rangle$ in the unit sphere of $X$, this exists by separability of $X$. Let $B'$ be the unit ball in the dual space. By the definition of the weak*-topology we have a continuous map $f_n \colon B' \to D$ given by $f_n(\varphi) = \varphi(x_n)$ where $D = \{z \in \mathbb{C} : |z| \leq 1\}$ is the closed unit disc in $\mathbb{C}$. These assemble to a continuous map $f \colon B' \to D^{\mathbb{N}}$ given by
$$f(\varphi) = \langle f_n(\varphi) : n \in \mathbb{N}\rangle = \langle \varphi(x_n) : n \in \mathbb{N}\rangle$$ by the definition of the product topology on $D^\mathbb{N}$. I claim that this map is injective. Indeed, if $\varphi_1 \neq \varphi_2$ then there is $x \in X$ such that $\varphi_1(x) \neq \varphi_2(x)$. Normalizing $x$ we can assume hat $\|x\| = 1$. By choosing $x_n$ close enough to $x$ we will have $\varphi_1(x_n) \neq \varphi_2(x_n)$. This implies that $f(\varphi_1) \neq f(\varphi_2)$ and we're done.
To be a little more explicit, the standard metric on $D^\mathbb{N}$ is $d(a,b) = \sum_{n=1}^\infty 2^{-n} |a_n - b_n|$ and since $f$ is injective and continuous, $\delta(\varphi_1,\varphi_2) = d(f(\varphi_1),f(\varphi_2))$ is a continuous metric on $B'$ with the weak*-topology and this shows metrizability of $B'$.
We assumed Alaoglu's theorem. If we don't do that there are two more things to do:
- show that convergence with respect to $\delta$ is equivalent to weak*-convergence.
- show that $B'$ is compact with respect to $\delta$.