There appear to be two senses of the qualifier "Archimedean" for fields. One is for ordered fields, and one is for "valued fields" (fields with an absolute value function defined). In the first case, the field is said to be "Archimedean" iff there exist no elements $x$ for which $nx < 1$ for every natural number $n$ and which are yet not equal to zero. Intuitively, we can think of such an element, if one existed, as being "infinitely small". If such elements exist, then the field is non-Archimedean.
The other sense deals with so-called valued fields. Instead of an order, we have an "absolute value function" which returns a real number and satisfies properties you'd expect such a thing to satisfy. Once again we have another formulation of the "Archimedean" property: the field is Archimedean iff there are no elements $x$ such that $|nx| < 1$ for every natural number $n$ and which are yet not equal to zero, and otherwise is non-Archimedean. Yet what is the intuition behind this, when the absolute value, which one may think of as a sort of "size measurement" of an element in some sense, must be a good ol' real number, and so surely can't be "infinitely small" and yet nonzero? In a non-Archimedean valued field, the absolute value function satisfies the inequality $|x + y| \le \max\{|x|, |y|\}$, which makes its behavior very strange... in particular, given a sequence of $|x|$, $|x + x|$, $|x + x + x|$, ..., the absolute value must at the very least not grow (the above inequality tells us $|x + x| \le |x|$, and induction does the rest), and may even shrink! Very weird indeed!