Assume for a contradiction that $\sup X > \sup Y$.
I claim that in this case there is some $q \in X$ that lies in the interval $\left(\sup Y, \sup X\right]$. If there was no such $q$, then $\sup Y$ would be an upper bound of $X$, so the least upper bound of $X$, $\sup X$, would be smaller than $\sup Y$, contradicting our assumption.
But for any $x \in X$ there is some $y \in Y$ with $x \leq y$. Take such a $y$ corresponding to $x=q$. Then $\sup Y < q \leq y$, so $\sup Y$ is smaller than some element of $Y$, a contradiction.
Since assuming $\sup X > \sup Y$ leads to a contradiction, we have $\sup X \leq \sup Y$.