If you want to distinguish between the two operands in statements such as
$$a \vee b$$
$$a \wedge b$$
the convention typically used is to call $a$ the "first operand" and $b$ the "second operand." If the operator is conjunction, then one could say $a$ is the "first conjunct" and $b$ is the "second conjunct." If the operator is disjunction, then one could say $a$ is the "first disjunct" and $b$ is the "second disjunct." All of these are equivalent in meaning. Note that due to commutativity $a$ or $b$ could easily be listed as the first or second operand, so the choice of which is arbitrary.