A semigroup is a set $S$ together with an associative binary operation $m:S\times S\rightarrow S$.
In any kind of semigroup I can think of (group, ring, field, etc), this binary operation $m$ is not invertible.
If $|S|<\infty$, then $m$ cannot be invertible. Edit: Wrong! See accepted answer.
I would be interested in an example of semigroup such that $m$ is invertible... or a proof that no such object exists.
In such a semigroup, unless I am being an idiot, associativity is equivalent to
$$m\times \operatorname{id}_S=\operatorname{id}_S\times m.$$
I was going to say this is a kind of commutativity. Now I realise this is nonsense... but I still think it might be interesting to come up with a semigroup with invertible $m$.
You may assume the axiom of choice.