$T:(X,\lVert \cdot \rVert)\rightarrow (Y,\lVert \cdot \rVert)$ is continuous if and only if $ T: (X,\sigma(X,X^*))\rightarrow (Y,\sigma(Y,Y^*)) $ is continuous.
$(\Rightarrow) $ $ T: (X,\sigma(X,X^*))\rightarrow (Y,\sigma(Y,Y^*)) $ will be continuous if and only if $y^*\circ T:(X,\sigma(X,X^*))\rightarrow \mathbb{R} $ is continuous for every $y^*\in Y^*$. However, because $T$ is continuous, $y^*\circ T\in X^*$ and this direction follows.
$(\Leftarrow)$ This is considerably harder. Let us prove some lemmas first.
Lemma 1: There are no extra continuous linear functionals in the weak topology. Precisely: $$(X,\sigma (X,X^*))^*=X^*$$
Proof: $X^*\subseteq (X,\sigma (X,X^*))^*$ by definition of the weak topology. Now take $g\in (X,\sigma (X,X^*))^*$. If $g\equiv 0$, we are done. Suppose there is $x_o\in (\ker g)^C$. Because $\ker g$ is closed in the weak topology we have:
$$x_o\in \cap_{i=1}^n \{x| \:|f_i(x)-f_i(x_o)|<\varepsilon\}\subseteq (\ker g)^C$$
If it doesn't hold that $\cap_{i=1}^n \ker f_i \subseteq \ker g$ there is a certain $x$ satisfying $f_i(x)=0$ for every $i$ and $g(x) \not=0$. But this means that $x_o+\lambda x\in (\ker g)^C$ for every $\lambda$, which is absurd, say $\lambda=-g(x_o)/g(x)$. Hence $\cap_{i=1}^n \ker f_i \subseteq \ker g$ and by this result, we have, $g=\sum_i \lambda_i f_i\in X^*$ and we are done.
Lemma 2: weak convergence implies norm boundedness.
Proof: This has been done in other MSE posts. Brezis also does this as a consequence of the uniform boundedness principle.
Finally let us prove our result. Because $y^*\circ T$ is continuos with respect to $\sigma(X,X^*)$, by Lemma 1, we have $y^*\circ T \in X^*$. Suppose by way of contradiction that there are $x_n$ in the circle with $\lVert T(x_n)\rVert \geq n$. Clearly:
$$\frac{x_n}{\sqrt{\lVert T(x_n) \rVert}}\rightarrow 0$$
But because $y^*\circ T\in X^* $, this implies:
$$y^*\left(\frac{T(x_n)}{\sqrt{\lVert T(x_n) \rVert}}\right)\rightarrow 0\quad \text{but $y\in Y^*$ is arbitrary, so:}\quad \frac{T(x_n)}{\sqrt{\lVert T(x_n)\rVert}}\rightharpoonup 0$$
But by Lemma 2 this means:
$$\sqrt{n}\leq \left\lVert \frac{T(x_n)}{\sqrt{\lVert T(x_n)\rVert}}\right \rVert \leq C$$
This contradiction implies $T$ must be bounded.